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        純度:99% 包裝:25kg/桶

        CAS:           867-44-7
        分子式:       C2H6N2S·0.5H2SO4
        結構式:       [CH2SC(=NH)NH2]2·H2SO4
        分子量:       140.19

        中文名稱:    S-甲基異硫脲硫酸鹽

        英文名稱:    2-methyl-2-thio-pseudoure sulfate
                             carbamimidothioic acid, methyl ester, sulfate
                             s-methylisothiuronium sulfate
        性質描述:  針狀結晶。熔點244℃(分解)。能溶于熱水,不溶于醇。其游離基S-甲基異硫脲[2986-19-8]不能單離;其鹽酸鹽[53114-57-1]熔點為59-60℃。


        用途:   該品為有機合成的中間體。醫藥工業用于生產抗癌藥物5-氟脲嘧啶、丙脒腙、硫酸羥胍,降壓藥胍氯酚等;農藥工業用于生產殺菌劑多菌靈、苯菌靈及殺蟲劑甲基嘧啶磷等。


        Product Identification
        【Product Name】2-Methyl-2-thiopseudourea sulfate
        【Synonyms】S-Methylisothiourea hemisulfate;S-甲基異硫脲硫酸鹽
        【Molecular Weight】278.37
        【RTECS Class】Drug
        【Beilstein Reference】4-03-00-00358
        【EC Class】harmful

        Physical and Chemical Properties
        【Appearance】White solid.
        【Solubility in water】260 g/L (20℃)
        【Melting Point】240 - 241℃
        【Density】1.28 g/cm3 (20℃)

        First Aid Measures
        【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
        【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
        【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
        【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

        Handling and Storage

        Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
        【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

        Hazards Identification
        【Ingestion】May cause digestive tract disturbances.
        【Inhalation】May cause respiratory tract irritation.
        【Skin】May cause skin irritation.
        【Eyes】May cause eye irritation.
        【EC Risk Phrase】R 22
        【EC Safety Phrase】S 22 36/37

        Exposure Controls/Personal Protection
        【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
        【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

        Fire Fighting Measures
        【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

        Accidental Release Measures
        【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

        Stability and Reactivity
        【Disposal Code】3
        【Stability】Stable under normal temperatures and pressures.
        【Incompatibilities】Strong oxidizing agents.
        【Decomposition】Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, nitrogen.

        Transport Information
        【HS Code】2930 90 70


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